MATL, 12 bytes

q:Q"@Z\l_)vs

Try it at MATL Online

Explanation

        % Implicitly grab input (N)
q       % Subtract one
:       % Create an array [1...(N-1)]
Q       % Add one to create [2...N]
"       % For each element
  @Z\   % Compute the divisors of this element (including itself)
  l_)   % Grab the next to last element (the largest that isn't itself)
  v     % Vertically concatenate the entire stack so far
  s     % Sum the result

MATL, 12 bytes

q:Q"@Z\l_)vs

Try it at MATL Online

Explanation

        % Implicitly grab input (N)
q       % Subtract one
:       % Create an array [1...(N-1)]
Q       % Add one to create [2...N]
"       % For each element
  @Z\   % Compute the divisors of this element (including itself)
  l_)   % Grab the next to last element (the largest that isn't itself)
  v     % Vertically concatenate the entire stack so far
  s     % Sum the result

#MATL, 12 bytes

q:Q"@Z\l_)vs

Try it at MATL Online

Explanation

        % Implicitly grab input (N)
q       % Subtract one
:       % Create an array [1...(N-1)]
Q       % Add one to create [2...N]
"       % For each element
  @Z\   % Compute the divisors of this element (including itself)
  l_)   % Grab the next to last element (the largest that isn't itself)
  v     % Vertically concatenate the entire stack so far
  s     % Sum the result

MATL, 12 bytes

q:Q"@Z\l_)vs

Try it at MATL Online

Explanation

        % Implicitly grab input (N)
q       % Subtract one
:       % Create an array [1...(N-1)]
Q       % Add one to create [2...N]
"       % For each element
  @Z\   % Compute the divisors of this element (including itself)
  l_)   % Grab the next to last element (the largest that isn't itself)
  v     % Vertically concatenate the entire stack so far
  s     % Sum the result