##Actually, 18 bytes
5Pτ;r;∙`MúE`M╪k♂Σi
-4 bytes from Leaky Nun, and the inspiration for 4 more
Explanation:
5Pτ;r;∙`MúE`M╪k♂Σi
5Pτ; two copies of 26
r; consume a copy for range(26), duplicate that
∙ Cartesian product
`MúE`M for each (x,y) pair:
M maximum
úE element in lowercase English alphabet
╪k list of length-26 sublists
♂Σ concatenate strings in each sublist
i flatten and implictly print the stack