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#Java, 67 bytes

s->!s.stream().anyMatch(p->s.stream().anyMatch(q->s.contains(p+q)))

Input is a Set<Integer>. Tests:

import java.util.Arrays;
import java.util.Set;
import java.util.function.Function;
import java.util.stream.Collectors;

public class SumFree {
    public static void main(String[] args) {
        sumFree(s->!s.stream()
            .anyMatch(p->s.stream()
                .anyMatch(q->s.contains(p+q)))); // formatted to avoid wrapping
    }

    public static void sumFree(Function<Set<Integer>, Boolean> func) {
        test(func);
        test(func, 4);
        test(func, 1, 5, 7);
        test(func, 16, 1, 4, 9);
        test(func, 1, 4, 5, 7);
        test(func, 0);
        test(func, 3, 0);
        test(func, 16, 1, 4, 8);
    }

    public static void test(Function<Set<Integer>, Boolean> func, Integer... vals) {
        Set<Integer> set = Arrays.stream(vals).collect(Collectors.toSet());
        System.out.format("%b %s%n", func.apply(set), set);
    }
}

Output:

true []
true [4]
true [1, 5, 7]
true [16, 1, 4, 9]
false [0]
false [1, 4, 5, 7]
false [0, 3]
false [16, 1, 4, 8]

Java, 67 bytes

s->!s.stream().anyMatch(p->s.stream().anyMatch(q->s.contains(p+q)))

Input is a Set<Integer>. Tests:

import java.util.Arrays;
import java.util.Set;
import java.util.function.Function;
import java.util.stream.Collectors;

public class SumFree {
    public static void main(String[] args) {
        sumFree(s->!s.stream()
            .anyMatch(p->s.stream()
                .anyMatch(q->s.contains(p+q)))); // formatted to avoid wrapping
    }

    public static void sumFree(Function<Set<Integer>, Boolean> func) {
        test(func);
        test(func, 4);
        test(func, 1, 5, 7);
        test(func, 16, 1, 4, 9);
        test(func, 1, 4, 5, 7);
        test(func, 0);
        test(func, 3, 0);
        test(func, 16, 1, 4, 8);
    }

    public static void test(Function<Set<Integer>, Boolean> func, Integer... vals) {
        Set<Integer> set = Arrays.stream(vals).collect(Collectors.toSet());
        System.out.format("%b %s%n", func.apply(set), set);
    }
}

Output:

true []
true [4]
true [1, 5, 7]
true [16, 1, 4, 9]
false [0]
false [1, 4, 5, 7]
false [0, 3]
false [16, 1, 4, 8]

s->!s.stream().anyMatch(p->s.stream().anyMatch(q->s.contains(p+q)))

import java.util.Arrays;
import java.util.Set;
import java.util.function.Function;
import java.util.stream.Collectors;

public class SumFree {
    public static void main(String[] args) {
        sumFree(s->!s.stream()
            .anyMatch(p->s.stream()
                .anyMatch(q->s.contains(p+q)))); // formatted to avoid wrapping
    }

    public static void sumFree(Function<Set<Integer>, Boolean> func) {
        test(func);
        test(func, 4);
        test(func, 1, 5, 7);
        test(func, 16, 1, 4, 9);
        test(func, 1, 4, 5, 7);
        test(func, 0);
        test(func, 3, 0);
        test(func, 16, 1, 4, 8);
    }

    public static void test(Function<Set<Integer>, Boolean> func, Integer... vals) {
        Set<Integer> set = Arrays.stream(vals).collect(Collectors.toSet());
        System.out.format("%b %s%n", func.apply(set), set);
    }
}

s->!s.stream().anyMatch(p->s.stream().anyMatch(q->s.contains(p+q)))

import java.util.Arrays;
import java.util.Set;
import java.util.function.Function;
import java.util.stream.Collectors;

public class SumFree {
    public static void main(String[] args) {
        sumFree(s->!s.stream()
            .anyMatch(p->s.stream()
                .anyMatch(q->s.contains(p+q)))); // formatted to avoid wrapping
    }

    public static void sumFree(Function<Set<Integer>, Boolean> func) {
        test(func);
        test(func, 4);
        test(func, 1, 5, 7);
        test(func, 16, 1, 4, 9);
        test(func, 1, 4, 5, 7);
        test(func, 0);
        test(func, 3, 0);
        test(func, 16, 1, 4, 8);
    }

    public static void test(Function<Set<Integer>, Boolean> func, Integer... vals) {
        Set<Integer> set = Arrays.stream(vals).collect(Collectors.toSet());
        System.out.format("%b %s%n", func.apply(set), set);
    }
}

#Java, 67 bytes

s->!s.stream().anyMatch(p->s.stream().anyMatch(q->s.contains(p+q)))

#Java, 67 bytes

s->!s.stream().anyMatch(p->s.stream().anyMatch(q->s.contains(p+q)))

Input is a Set<Integer>. Tests:

import java.util.Arrays;
import java.util.Set;
import java.util.function.Function;
import java.util.stream.Collectors;

public class SumFree {
    public static void main(String[] args) {
        sumFree(s->!s.stream()
            .anyMatch(p->s.stream()
                .anyMatch(q->s.contains(p+q)))); // formatted to avoid wrapping
    }

    public static void sumFree(Function<Set<Integer>, Boolean> func) {
        test(func);
        test(func, 4);
        test(func, 1, 5, 7);
        test(func, 16, 1, 4, 9);
        test(func, 1, 4, 5, 7);
        test(func, 0);
        test(func, 3, 0);
        test(func, 16, 1, 4, 8);
    }

    public static void test(Function<Set<Integer>, Boolean> func, Integer... vals) {
        Set<Integer> set = Arrays.stream(vals).collect(Collectors.toSet());
        System.out.format("%b %s%n", func.apply(set), set);
    }
}

Output:

true []
true [4]
true [1, 5, 7]
true [16, 1, 4, 9]
false [0]
false [1, 4, 5, 7]
false [0, 3]
false [16, 1, 4, 8]