Python 3, 2727 26 bytes
Code
lambda v:sum(v)/2-2*minmin(v)>12>6
Outputs True
for cheated and False
for valid.
Explanation
Let \$a\$, \$b\$ and \$c\$ be the three dice rolls, where \$a\$ is the highest roll. Therefore, if \$a > 6\$, the alien cheated, and otherwise they did not.
The sum of the numbers is \$2a + 2b + 2c\$. The minimum of the numbers is \$b + c\$. Therefore, sum(v)/2-2*minmin(v)
is \$(2a + 2b + 2c) - 2(b + c)\$\$(2a + 2b + 2c)/2 - (b + c)\$ which is \$2a\$\$a\$. If this is greater than \$12\$\$6\$, the alien cheated.