GolfScript, 1313 12 bytes
{48-}/]10base%10base
{ }/ % # For each byte in the input
48- # Subtract 48
] # Put all results in an array
10base # Convert to base 10
Alternative 13 byte solution:
0\{48-\10*+}/
0\ # Put 0 under the input
{ }/ # For each byte in the input
48- # Subtract 48
\10* # Multiply the output by 10
+ # Add the subtracted ASCII